When a person dies without a will, then the next of kin must petition the court or go to the register of wills to obtain letters of administration. Once you have received letters of administration, you can then act for the estate. This will allow you to transfer the real estate and other assets of the decedent in accordance with the laws of intestate succession of the state of the decedent. You need to retain an estates lawyer to assist you or at least call the register of wills in the county in question to get more information about their procedures for obtaining letters of administration.
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You will need to file a petition for administration of your brother's estate in the county in which he was a resident at the time of his death. You will be required to notify all of his heirs (this includes lineal descendants including his spouse, children, grandchildren,etc., but NOT siblings, parents, cousins, etc.) of your petition and intent to administer the estate. If he had land in another state, you may also be required to petition for something known as "ancillary probate," in which you will file a petition to administer in the state in which the land is located as well. There are several rules regarding who needs to notified and how, how and when assets can be distributed or sold, and the priority of claims against the estate. You should be aware that as the administrator of the estate, you are a fiduciary, meaning you may be held personally liable for mismanagement of the estate. If you do not feel comfortable navigating the probate process on your own, you should seek the assistance of an attorney experienced in probate matters.